| [1] | METCALF & EDDY / EPA — wastewater disinfection: dose 5–20 mg/L for secondary effluent, residual 0.5–2 mg/L (up to 5 for chloramine), contact 20–30 min at peak flow. |
| [2] | Breakpoint chlorination: Cl₂:NH₃-N ≈ 7.6:1 by weight to reach the breakpoint and leave free residual; monochloramine formation sits around Cl₂:N ≈ 3–5:1. Other reducing demand taken as ≈0.3·BOD + 1 mg/L. |
| [3] | CT values at 20 °C, pH 7 (mg·min/L) — free chlorine: coliform 2-log ≈1.5, virus 3-log ≈5, Giardia 3-log ≈53. Chloramine: ≈50, ≈750, ≈1100 respectively. Temperature: CT ∝ 1.07(20−T) (matches EPA tables from 5 to 25 °C). |
| [4] | pH: CT scales as ≈1.25(pH−7), reflecting the HOCl/OCl⁻ split (HOCl ≈76 % at pH 7, ≈24 % at pH 8). |
| [5] | Baffling factor T10/τ: unbaffled 0.1, poor 0.3, average 0.5, superior 0.7, plug flow 1.0. Design on T10, not on the nominal HRT. |
| [6] | Turbidity shields pathogens and consumes chlorine; keep effluent below about 2 NTU, ideally under 1 NTU, before disinfection. |
| [7] | Disinfection by-products: THM formation rises with dose and TOC. Watch it above roughly 10 mg/L dose with TOC above 5 mg/L. |
| [8] | Sodium hypochlorite: 5–15 % available chlorine; it decays with age, heat and light — size storage for turnover, not for calendar weeks. Dechlorination: NaHSO₃ ≈1.46 mg per mg Cl₂, SO₂ ≈0.9 mg per mg Cl₂. |